CC-stretched formic acid: isomerisation, dimerisation, and carboxylic acid complexation

نویسندگان

چکیده

The cis – trans -isomerism of the propiolic acid monomer (HCC–COOH) is examined with linear Raman jet spectroscopy, yielding first environment-free vibrational band centres a higher-energy -rotamer beyond formic (HCOOH) in addition to all fundamentals and large number hot combination/overtone bands -conformer.

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2021

ISSN: ['1463-9076', '1463-9084']

DOI: https://doi.org/10.1039/d1cp02700j